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Transition-Metal-Free Cross-Dehydrogenative Couplings of 8-Aminoquinoline Amides at C5 Position with Acetonitrile, Ethers or Acetone
European Journal of Organic Chemistry  (IF3.021),  Pub Date : 2021-09-09, DOI: 10.1002/ejoc.202100953
Da Liu, Zhen Xia, Yuanjiu Xiao, Yongqi Yu, Lin Yu, Zenan Song, Qianlong Wu, Junhui Zhang, Ze Tan

A novel and efficient method for highly regioselective cyanomethylation, etherification or acetonation of 8-aminoquinoline amides at C5 position was developed, and such reactions proceed under transition metal-free and base-free conditions.