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Example:10.1021/acsami.1c06204 or Chem. Rev., 2007, 107, 2411-2502
Micro-Mesoporous Catalyst Based on Natural Aluminosilicate Nanotubes and ZSM-5 Zeolite for Methanol Conversion to Hydrocarbons
Petroleum Chemistry  (IF1.029),  Pub Date : 2021-07-07, DOI: 10.1134/s0965544121070082
E. M. Smirnova, D. P. Melnikov, N. R. Demikhova, M. I. Rubtsova, S. S. Boev, E. E. Brindukova, A. P. Glotov, V. A. Vinokurov

Abstract

A methanol conversion catalyst based on natural aluminosilicate nanotubes and H–ZSM-5 zeolite was synthesized. Its textural, structural, and acid properties were studied by low-temperature nitrogen adsorption–desorption, transmission electron microscopy, X-ray diffraction analysis, and temperature-programmed ammonia desorption. The influence exerted on the methanol conversion and product distribution by the reaction temperature (380–460°С), pressure (0.1–0.5 MPa), and feed space velocity (0.5–1 h–1) was studied. The catalyst based on halloysite aluminosilicate nanotubes showed high selectivity in formation of both lower olefins and aromatic hydrocarbons.