Example：10.1021/acsami.1c06204 or Chem. Rev., 2007, 107, 2411-2502
Phthalocyanine‐Based 2D Conjugated Metal‐Organic Framework Nanosheets for High‐Performance Micro‐Supercapacitors Advanced Functional Materials (IF18.808), Pub Date : 2020-06-11, DOI: 10.1002/adfm.202002664 Mingchao Wang, Huanhuan Shi, Panpan Zhang, Zhongquan Liao, Mao Wang, Haixia Zhong, Friedrich Schwotzer, Ali Shaygan Nia, Ehrenfried Zschech, Shengqiang Zhou, Stefan Kaskel, Renhao Dong, Xinliang Feng
2D conjugated metal‐organic frameworks (2D c‐MOFs) are emerging as a novel class of conductive redox‐active materials for electrochemical energy storage. However, developing 2D c‐MOFs as flexible thin‐film electrodes have been largely limited, due to the lack of capability of solution‐processing and integration into nanodevices arising from the rigid powder samples by solvothermal synthesis. Here, the synthesis of phthalocyanine‐based 2D c‐MOF (Ni2[CuPc(NH)8]) nanosheets through ball milling mechanical exfoliation method are reported. The nanosheets feature with average lateral size of ≈160 nm and mean thickness of ≈7 nm (≈10 layers), and exhibit high crystallinity and chemical stability as well as a p‐type semiconducting behavior with mobility of ≈1.5 cm2 V−1 s−1 at room temperature. Benefiting from the ultrathin feature, the nanosheets allow high utilization of active sites and facile solution‐processability. Thus, micro‐supercapacitor (MSC) devices are fabricated mixing Ni2[CuPc(NH)8] nanosheets with exfoliated graphene, which display outstanding cycling stability and a high areal capacitance up to 18.9 mF cm−2; the performance surpasses most of the reported conducting polymers‐based and 2D materials‐based MSCs.